;6.2) Program: 19F-13C HETCOR ;Description: One-bond correlations of 19F and 13C peak positions in fluoropolymers ;Requires: !!!!; little difficulty after 6.1) ;Reference(s): Chen & KSR, Macromolecules 2004 ;sr19Fcpp.ramp (XWinNMR 2.6) ;from sr19Fcpp.ramp on SGI ;type "eda", set "CPDPRG2" to "tppm15", set p30=p31=9u (180 on 1F at pl12) ;with pulsed 19F decoupling (1 180 pulse per rotation period) ; at high spin rate (28 kHz works well) ;ramp on 1H during CP "d26=0.001s/l30" ;1tr "d28=d26-p8" ;1 tr for decoupling "l1=aq/d26" 1 ze 2 d1 do:f2 ;recycle delay 10u pl1:f1 10u pl2:f2 ;preselect pl2 drive power for F2 2u:f2 ph1 2u:f1 ph2 p3:f2 ph1 ;proton 90 pulse 1u ;pl3:f2 (p15 ph2):f1 (p15:sp1 ph10):f2 ;CP contact time 1u pl12:f2 2u:f1 ph0 ;dead time delay, reset RF phase to detect 2u adc ph31 ;start ADC with ph31 signal routing 3 d28 ;detection p8:f2 ph14^ ;19F 180 pulse (or write this into cpd file) lo to 3 times l1 rcyc=2 ;do NS scans wr #0 exit ph0= 0 ;reference phase ph1= +y -y ph2= +x +x +y +y -x -x -y -y ;ph2= +x ph10= +x ;ph14= +x +y +y +x +x +y +y +x ;original used for first Macromolecules paper ; -x -y -y -x -x -y -y -x ph14= +x +y +x +y +y +x +y +x ;xy-8 -x -y -x -y -y -x -y -x ph31= 0 2 1 3 2 0 3 1