Carbon Nitride Nanothread Crystals Derived from Pyridine

Author(s)
X. Li , T. Wang , Pu Duan , M. Baldini , H.-T. Huang , B. Chen , D. Koeplinger , Vincent H. Crespi , Klaus Schmidt-Rohr , R. Hoffmann , M. Guthrie and J. V. Badding #
Publisher
J. Am. Chem. Soc.
Year
2018
Volume
140
Pages
4969-4972
DOI
https://doi.org/10.1021/jacs.7b13247

Abstract

Carbon nanothreads are a new one-dimensional sp3 carbon nanomaterial. They assemble into hexagonal crystals in a room temperature, nontopochemical solid-state reaction induced by slow compression of benzene to 23 GPa. Here we show that pyridine also reacts under compression to form a well-ordered sp3 product: C5NH5 carbon nitride nanothreads. Solid pyridine has a different crystal structure from solid benzene, so the nontopochemical formation of low-dimensional crystalline solids by slow compression of small aromatics may be a general phenomenon that enables chemical design of properties. The nitrogen in the carbon nitride nanothreads may improve processability, alters photoluminescence, and is predicted to reduce the bandgap.